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Depending on the type of nanoparticles introduced into polymeric materials in low concentrations, nanocomposites acquire special chemical, electrophysical, thermal and tribological properties, which opens up wide possibilities for their use in electronic engineering technology. However, with an increase in the volume fraction of the dispersed phase above a certain value, sharp changes in the physicochemical properties of the material occur. The observed phenomenon can be explained by the rearrangement of the nanocomposite structure due to the processes of agglomeration of dispersed phase particles, or of a nanocomposite structure formation in the form of a continuous network. In this work, a theoretical assessment is performed of the critical value of the dispersed phase volume fraction in the nanocomposite, at which the specified structural rearrangement begins, depending on the size of the particles of this phase. The thicknesses of monomolecular layers of various polymer matrices are estimated using calculation methods based on ideas about the possible shapes of polymer molecules on the surface of the solid phase. Based on the calculation results, graphs of the dependence of the critical value of the volume fraction of the dispersed phase of the nanocomposite on the size of its particles for matrices based on polyimide and epoxy resins were constructed. It has been demonstrated that calculated dependence for the thickness of oligomer layer around dispersed phase particle equal to 200 nm found good agreement with experimental record.

Key words: nanocomposite, polymer, redistribution layers, microassembly, internal assembly of crystals
Published in: ELECTRONICS MATERIALS
Bibliography link: Borisov А. G., Vertyanov D. V., Ilyasheva E. V., Osipenkova N. G., Timoshenkov S. P. Features of the properties of polymer composites based on a nanosized dispersed phase. Izv. vuzov. Elektronika = Proc. Univ. Electronics. 2025;30(5):566–574. (In Russ.). https://doi.org/10.24151/1561-5405-2025-30-5-566-574.
Financial source: the work has been supported by the Russian Science Foundation (project 23-29-00964).

Alexander G. Borisov
National Research University of Electronic Technology (Russia, 124498, Moscow, Zelenograd, Shokin sq., 1)

Denis V. Vertyanov
National Research University of Electronic Technology (Russia, 124498, Moscow, Zelenograd, Shokin sq., 1)

Ekaterina V. Ilyasheva
National Research University of Electronic Technology (Russia, 124498, Moscow, Zelenograd, Shokin sq., 1)

Natalia G. Osipenkova
National Research University of Electronic Technology (Russia, 124498, Moscow, Zelenograd, Shokin sq., 1)

Sergey P. Timoshenkov
National Research University of Electronic Technology (Russia, 124498, Moscow, Zelenograd, Shokin sq., 1)

1. Белоус А. И., Паньков А. А. Корпусирование микроэлектронных приборов: технологии, конструкции, оборудование. М.: Техносфера; 2023. 558 с. EDN: DPSQGT.

Belous A. I., Pankov A. A. Packaging of microelectronic devices: Technologies, constructions, equipment. Moscow: Tekhnosfera Publ.; 2023. 558 p. (In Russ.).

2. Кравцова В. Д., Умерзакова М. Б., Коробова Н. Е., Вертянов Д. В. Медьсодержащие композиции на основе алициклического полиимида для микроэлектроники. Изв. вузов. Электроника. 2017;22(6):509–517. https://doi.org/10.24151/1561-5405-2017-22-6-509-517. EDN: ZWPZIJ.

Kravtsova V. D., Umerzakova M. B., Korobova N. E., Vertyanov D. V. Copper-containing compositions based on alicyclic polyimide for microelectronics. Izv. vuzov. Elektronika = Proc. Univ. Electronics. 2017;22(6):509–517. (In Russ.). https://doi.org/10.24151/1561-5405-2017-22-6-509-517

3. Vertyanov D. V., Korobova N. E., Pogudkin A. V., Kravtsova V. D. Physical and technological characteristic features of the process of installation of dies onto a temporary foundation in internal wiring technology. Tech. Phys. 2020;65(10):1677–1684. https://doi.org/10.1134/S1063784220100230

4. Иржак В. И. Эпоксидные полимеры и нанокомпозиты. Черноголовка: ИПХФ РАН; 2021. 318 с.

Irzhak V. I. Epoxy polymers and nanocomposites. Chernogolovka: IPKhF RAN Publ.; 2021. 318 p. (In Russ.).

5. Кербер М. Л. (ред.). Технология переработки полимеров. Физические и химические процессы: учеб. пособие для вузов. 2-е изд., испр. и доп. М.: Юрайт; 2024. 316 с.

Kerber M. L. (ed.). Polymer processing technology. Physical and chemical processes: study guide for universities. 2nd ed., rev. and upd. Moscow: Yurait Publ.; 2024. 316 p. (In Russ.).

6. Тагер А. А. Физико-химия полимеров. Изд. 4-е, перераб. и доп. М.: Научный мир, 2007. 576 с. EDN: QKBTHB.

Tager A. A. Physical chemistry of polymers. 4th ed., rev. and upd. Moscow: Nauchnyy mir Publ.; 2007. 576 p. (In Russ.).

7. Аржаков М. С., Зезин А. Б. (авт., ред.), Антипина А. Д. и др. Высокомолекулярные соединения: учебник и практикум для вузов. М.: Юрайт; 2024. 386 с.

Arzhakov M. S., Zezin A. B. (auth., ed.), Antipina A. D. et al. Macromolecular compounds: textbook and practical course for universities. Moscow: Yurait Publ.; 2024. 386 p. (In Russ.).

8. Василенко Н. А., Ахметьева Е. И., Свиридов Е. Б., Берендяев В. И., Рогожкина Е. Д., Алкаева О. Ф. и др. Растворимые полиимиды на основе 4,4'-диаминотрифениламина. Синтез, молекулярно-массовые характеристики, свойства растворов. Высокомолекулярные соединения. Серия А. 1991;33(7):1549–1560. EDN: XOJCRO.

Vasilenko N. A., Akhmet’eva Ye. I., Sviridov Ye. B., Berendyayev V. I., Rogozhkina Ye. D., Alkayeva O. F. et al. Soluble polyimides based on 4,4′-diaminotriphenylamine. Synthesis, molecular mass characteristics and solution properties. Polymer Science U.S.S.R. 1991;33(7):1439–1450. https://doi.org/10.1016/0032-3950(91)90333-L

9. Адрова Н. А., Бессонов М. И., Лайус Л. А., Рудаков А. П. Полиимиды – новый класс термостойких полимеров. Л.: Наука; 1968. 211 с.

Adrova N. A. et al. Polyimides: New class of heat-resistant polymers. Jerusalem: IPST, 1969. 168 p.

10. Масимов Э. А., Пашаев Б. Г., Раджабов М. Р. Определение конформации и размеров макромолекул ПЭГ в системах вода–ПЭГ–NaOH методом вискозиметрии. Журнал физической химии. 2021;95(1):57–62. https://doi.org/10.31857/S0044453721010180. EDN: KNPHLW.

Masimov E. A., Pashayev B. G., Rajabov M. R. Determining the conformation and dimensions of the PEG macromolecule in water–PEG–NaOH systems via vicosometry. Russ. J. Phys. Chem. A. 2021;95(1):84–89. https://doi.org/10.1134/S0036024421010180

11. Морозова С. М. Ионные конденсационные полимеры: дис. … канд. хим. наук. М., 2018. 182 с. EDN: ULTJBP.

Morozova S. M. Ionic condensation polymers: diss. for the Cand. Sci. (Chem.). Moscow, 2018. 182 p. (In Russ.).

12. Conformal coating. DeepMaterial. Available at: https://www.pottingcompound.com/conformal-coating/ (accessed: 16.06.2025).

13. Хозин В. Г. Усиление эпоксидных полимеров. Казань: Дом печати; 2004. 446 с.

Khozin V. G. Strengthening of epoxy polymers. Kazan: Dom pechati Publ.; 2004. 446 p. (In Russ.).

14. Равдель А. А., Пономарева А. М. (ред.) Краткий справочник физико-химических величин. 10-е изд., испр. и доп. СПб.: Иван Федоров; 2002. 237 с.

Ravdel A. A., Ponomareva A. M. (ed.) Short reference book of physical and chemical quantities. 10th ed., rev. and upd. St. Petersburg: Ivan Fedorov; 2002. 237 p. (In Russ.).

15. Хозин В. Г. Олигомерная предыстория структурообразования эпоксидных полимеров. Бутлеровские сообщения. 2006;8(3):36–49. EDN: KXSTGD.

Khozin V. G. Oligomer prehistory of structure formation of epoxy polymers. Butlerov Communications. 2006;8(3):36–49. (In Russ.). ROI: JBC-01/6-8-3-36.

Information about the publication

UDK: 620.22-022.532
Publication type: Scientific article
Source lang: Russian
DOI: 10.24151/1561-5405-2025-30-5-566-574
RISC id: YEUJVM

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